Genesis of chlorine and sulphur in fumarolic emissions at Vulcano Island (Italy): assessment of pH and redox conditions in the hydrothermal system     

V. Di Liberto  P. M. Nuccio  A. Paonita   《Journal of Volcanology and Geothermal Research》2002,116(1-2)

Chlorine- and sulphur-bearing compounds in fumarole discharges of the La Fossa crater at Vulcano Island (Italy) can be modelled by a mixing process between magmatic gases and vapour from a boiling hydrothermal system. This allows estimating the compounds in both endmembers. Magma degassing cannot explain the time variation of sulphur and HCl concentrations in the deep endmember, which are more probably linked to reactions of solid phases at depth, before mixing with the hydrothermal vapours. Based on the P–T conditions and speciation of the boiling hydrothermal system below La Fossa, the HCl and S_tot contents in the hydrothermal vapours were used to compute the redox conditions and pH of the aqueous solution. The results suggest that the haematite–magnetite buffer controls the hydrothermal fO₂ values, while the pH has increased since the end of the 1970s. The main processes affecting pH values may be linked to Na–Ca exchanges between evolved seawater, feeding the boiling hydrothermal system, and local rocks. While Na is removed from water, calcium enters the solution, undergoes hydrolysis and produces HCl, lowering the pH of the water. The increasing water–rock ratio within the hydrothermal system lowers the Ca availability, so the aqueous solution becomes less acidic. Seawater flowing towards the boiling hydrothermal brine dissolves a large quantity of pyrite along its path. In the boiling hydrothermal system, dissolved sulphur precipitates as pyrite and anhydrite, and becomes partitioned in vapour phase as H₂S and SO₂. These results are in agreement with the paragenesis of hydrothermal alteration minerals recovered in drilled wells at Vulcano and are also in agreement with the isotopic composition of sulphur emitted by the crater fumaroles.  相似文献   

粤西罗定盆地南缘金矿流体包裹体特征及成因意义     

黄圭成  汪雄武 《华南地质与矿产》2003,(4):44-50

罗定盆地南缘的金矿脉石英和方解石中发育液相、气相和气液两相3种类型包裹体,以液相包裹体和气液包裹体为主。气液包裹体的气液比为5%～25%。包裹体盐度w(NaCl)为0.9%～10.6%,多数>5%,属于咸水-卤水。包裹体的均一温度显示,金矿有两个成矿阶段:第一阶段形成温度为172℃,第二阶段形成温度为122℃。氢氧同位素组成、流体包裹体成分显示成矿热液来源于大气降水。金矿形成于低温、浅成-超浅成环境,成矿热液可能经历了减压沸腾过程。金矿的成因类型属于浅成-超浅成低温热液型。  相似文献   

四川银矿床的成因类型及找矿方向     

何显刚  陈才金  李淑慧  练嘉玉  张兴润 《四川地质学报》2003,23(2):93-98

四川已发现银矿床35个，主要与铅、锌、铜共生或者为其伴生组份。笔者将四川银矿床初步划分为5个类型和9个亚类型。成矿时代以晚白垩世和晚三叠世为主。四川银矿的找矿方向主要是三江地区的德格—乡城深大断裂带和扬子地台西缘的攀西裂谷带。  相似文献   

内蒙古胜利煤田共生锗矿的成因地球化学初探   总被引：7，自引：0，他引：7  

杜刚  汤达祯  武文  孙培城  白云来  玄艳琴  黄俊 《现代地质》2003,17(4):453-458

用统计和作图的分析方法,对内蒙古胜利煤田中共生锗矿床的锗品位与挥发分、灰分、硫分的关系进行了研究。结果表明煤中锗品位与挥发分呈正相关、与原煤灰分负相关、与洗煤灰分正相关关系;全区煤属中硫煤,锗品位与原煤和洗煤硫分均呈正相关关系,煤的灰分指数较低(3 579);锗分布不均匀,富锗煤矿明显属于断裂坳陷边缘沉积,锗品位可以在煤层的顶部、中部、底部同时或单个部位呈现高值,大多数煤层中部出现锗高品位值,这有别于以往所报道的锗品位只在煤层顶、底部相对富集的研究结论。认为胜利煤田锗主要与有机质结合;锗的有利聚集条件是水动力较弱、地下水位较低、强还原的停滞沼泽环境;泥炭聚集阶段有机质的吸附作用是锗的主要富集机制。  相似文献   

鄂尔多斯盆地苏里格庙与靖边天然气单体碳同位素特征及其成因   总被引：7，自引：1，他引：7  

付锁堂  冯乔  张文正 《沉积学报》2003,21(3):528-532,538

苏里格庙上古生界砂岩气藏天然气重烃含量高,干燥系数低,为湿气;靖边奥陶系风化壳气藏天然气重烃含量低,干燥系数高,属干气。苏里格庙天然气的正构烷烃碳同位素具有δ13 C₁<δ13 C₃ <δ13 C₂ <δ13 C4的规律,靖边天然气具有δ13 C₁<δ13 C₂ <δ13 C₃ 的规律。二者高碳数烷烃的同位素差别较大,尤其是苏里格庙的乙烷碳同位素比靖边平均重 3.6‰。根据天然气单体碳同位素及其含量变化,苏里格庙天然气属煤成气,靖边天然气属煤成气与油型气的混合气。苏里格庙和靖边天然气中均含少量CO₂ 气,其碳同位素表明苏里格庙除苏 5井为无机CO₂ 气外,均为有机CO₂ 气;靖边林 1、林 5井为无机CO₂ 气,陕参 1井为有机CO₂ 气。结合烷烃气和CO₂ 气,苏里格庙天然气可以分为含有机CO₂ 煤成气和含无机CO₂ 煤成气。碳同位素比值与Ro 关系分析认为,苏里格庙的天然气成熟度处于成熟到高成熟阶段,其相应气源岩的平均Ro 为 1.2 9%～ 1.39%,这一结果与该区二叠系煤岩的成熟度符合较好。  相似文献   

The inversion of anelastic coefficient,source parameters and site respond using genetic algorithm     

刘杰  郑斯华  黄玉龙 《地震学报(英文版)》2003,16(2):226-232

It gradually becomes a common work using large seismic wave data to obtain source parameters, such as seismic moment, break radius, stress drop, with completingof digital seismic network in China (Hough, et al, 1999; Bindi, et al, 2001). These parameters are useful on earthquake prediction and seismic hazard analysis.Although the computation methods of source parameters are simple in principle and the many research works have been done, it is not easy to obtain the parameters accurately. There are two factors affecting the stability of computation results. The first one is the effect of spread path and site respond on signal. According to the research results, there are different geometrical spreading coefficients on different epicenter distance. The better method is to introduce trilinear geometrical spreading model (Atkinson, Mereu, 1992; Atkinson, Boore, 1995; WONG, et al, 2002). In addition, traditional site respond is estimated by comparing with rock station, such as linear inversion method (Andrews, 1982), but the comparative estimation will introduce some errors when selecting different stations. Some recent research results show that site respond is not flat for rock station (Moya, et al, 2000; ZHANG,. et al, 2001; JIN, et al, 2000; Dutta, et al, 2001). The second factor is to obtain low-frequency level and corner frequency fromdisplacement spectrum. Because the source spectrum model is nonlinear function,these values are obtained by eye. The subjectivity is strong. The small change of corner frequency will affect significantly the result of stress drop.  相似文献   

遗传算法与单纯形法组合的影像纹理分类方法   总被引：7，自引：3，他引：7  

郑肇葆 《测绘学报》2003,32(4):325-329

提出遗传算法(简称GA)与单纯形法组合的影像纹理分类方法(简称GASPX)。单纯形法是一种局部搜索方法，它通过反射，扩张，收缩操作，求得新的单纯形点，组成新单纯形，新单纯形比前一个单纯形更接近局部最优解。这种寻优方法收敛速度快，它与GA组合起来可以改善单独使用GA收敛速度慢的缺陷。由于在组合算法中是多个单纯形的局部区域的并行搜索，避免GA优化过程中过早收敛于局部最优解的现象出现。通过5种不同类别航空影像纹理识别的试验，并与GA的结果作对比，结果表明GASPX法优于GA法。  相似文献   

指派交叉--一种新的遗传交叉方法     

郑肇葆 《武汉大学学报(信息科学版)》2003,28(3):272-276

在用遗传算法生成影像纹理分类的“Tuned”模板中，引用了一个新的遗传交叉方法——指派交叉，与其他的交叉方法相比，指派交叉可在相同的搜索空间中提供更好的优化组合。试验证明，指派交叉是值得推广的一种遗传交叉方法。  相似文献   

遥感数据的遗传-超平面分割算法   总被引：2，自引：0，他引：2  

李启青  马建文  哈斯巴干  刘志丽  韩秀珍 《遥感学报》2003,7(6):485-489

在传统的采用超平面作为判别边界的分割方法中，使用统计学的方法确定类判别界面，当区域间的统计值大于区域内的统计值时，就会出现类判决界面难于确定的问题。遗传算法的特点是进行全局优化搜索，利用这种算法优势可以解决传统算法难以解决的超平面空间定位问题，从而解决类判决界面的确定问题。通过EOS／MODIS图像数据的分割对该方法作了详细的介绍，其分类精度明显高于统计学分类方法。  相似文献   

利用GPS位移和主应力方向观测资料进行川滇地区边界力的联合反演研究     

独知行  刘经南 《武汉大学学报(信息科学版)》2003,28(2):162-166,176

在简要介绍了川滇地区的构造格局和构造运动特征的基础上，讨论了不同观测数据同时用于反演的合理性和物理意义，利用1998～2000年观测的9个测点位移数据和1986年以前所测的10个主应力方向数据，将边界力和相对权比λ作为待反演参数，并考虑了主要活动断裂运动特性，进行了弹性有限元数值反演计算。计算结果表明，现今川滇地区的构造活动主要力源仍来源于印度板块与欧亚大陆的碰撞，菲律宾海板块的挤压作用也不可忽略，这一结论说明了该地区现今构造运动的继承性活动特征。  相似文献